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Diastereoselective Au-Catalyzed Allene Cycloisomerizations to Highly Substituted Cyclopentenes
Site- and regiocontrolled Au-catalyzed allene carbocyclizations furnish highly substituted cyclopentenes in >1:1 dr. Significant substitution on the substrate is tolerated, with potential to install five contiguous stereocenters after alkene functionalization. Major challenges include identifying...
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| Publicado no: | Org Lett |
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| Main Authors: | , , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2017
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC5542682/ https://ncbi.nlm.nih.gov/pubmed/28598168 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acs.orglett.7b01350 |
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