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Gold-Catalyzed Diastereoselective Cycloisomerization of Alkylidene Cyclopropane Bearing 1,6-Diynes()

An unprecedented gold-catalyzed diastereoselective cycloisomerization of 1,6-diynes bearing an alkylidene cyclopropane moiety has been developed. This methodology enables rapid access to a variety of 1,2-trimethylenenorbornanes, important building blocks in the preparations of abiotic and sesquiterp...

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Main Authors: Zheng, Hongchao, Adduci, Laura L., Felix, Ryan J., Gagné, Michel R.
Formato: Artigo
Idioma:Inglês
Publicado: 2014
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Acceso en liña:https://ncbi.nlm.nih.gov/pmc/articles/PMC4120096/
https://ncbi.nlm.nih.gov/pubmed/24920312
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201405147
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