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Mechanistic Pathways in Amide Activation: Flexible Synthesis of Oxazoles and Imidazoles
[Image: see text] The preparation of substituted aminooxazoles and aminoimidazoles from α-arylamides and α-aminoamides through triflic anhydride-mediated amide activation is reported. These reactions proceed via the intermediacy of nitrilium adducts and feature N-oxide-promoted umpolung of the α-pos...
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| Опубликовано в: : | Org Lett |
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| Главные авторы: | , , , , , |
| Формат: | Artigo |
| Язык: | Inglês |
| Опубликовано: |
American Chemical Society
2017
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| Online-ссылка: | https://ncbi.nlm.nih.gov/pmc/articles/PMC5525102/ https://ncbi.nlm.nih.gov/pubmed/28703599 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acs.orglett.7b01678 |
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