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Chiral Brønsted Acid‐Catalyzed Asymmetric Synthesis of N‐Aryl‐cis‐aziridine Carboxylate Esters

We report a multi‐component asymmetric Brønsted acid‐catalyzed aza‐Darzens reaction which is not limited to specific aromatic or heterocyclic aldehydes. Incorporating alkyl diazoacetates and, important for high ee's, ortho‐tert‐butoxyaniline our optimized reaction (i.e. solvent, temperature and...

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Bibliografski detalji
Izdano u:Angew Chem Int Ed Engl
Glavni autori: Bew, Sean P., Liddle, John, Hughes, David L., Pesce, Paolo, Thurston, Sean M.
Format: Artigo
Jezik:Inglês
Izdano: John Wiley and Sons Inc. 2017
Teme:
Online pristup:https://ncbi.nlm.nih.gov/pmc/articles/PMC5502890/
https://ncbi.nlm.nih.gov/pubmed/28378388
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201611990
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