Prehydrated One-Electron Attachment to Azido-Modified Pentafuranoses: Aminyl Radical Formation, Rapid H-Atom Transfer and Subsequent Ring Opening

Methyl 2-azido-2-deoxy-α-D-lyxofuranoside (1a) and methyl 2-azido-2-deoxy-β-D-ribofuranoside (2) were prepared from D-xylose or D-arabinose, respectively. Employing ESR and DFT/B3LYP/6-31G* calculations, we investigated (i) aminyl radical (RNH•) formation and (ii) reaction pathways of RNH•. Prehydra...

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Veröffentlicht in:J Phys Chem B
Hauptverfasser: Mudgal, Mukesh, Rishi, Sunny, Lumpuy, Daniel A., Curran, Keaton A., Verley, Kathryn Lynn, Sobczak, Adam J., Dang, Thao P., Sulimoff, Natasha, Kumar, Anil, Sevilla, Michael D., Wnuk, Stanislaw F., Adhikary, Amitava
Format: Artigo
Sprache:Inglês
Veröffentlicht: 2017
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Online Zugang:https://ncbi.nlm.nih.gov/pmc/articles/PMC5488683/
https://ncbi.nlm.nih.gov/pubmed/28425714
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acs.jpcb.7b01838
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