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Arylative Intramolecular Allylation of Ketones with 1,3‐Enynes Enabled by Catalytic Alkenyl‐to‐Allyl 1,4‐Rhodium(I) Migration

Alkenyl‐to‐allyl 1,4‐rhodium(I) migration enables the generation of nucleophilic allylrhodium(I) species by remote C−H activation. This new mode of reactivity was employed in the diastereoselective reaction of arylboron reagents with substrates containing a 1,3‐enyne tethered to a ketone, to give pr...

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Bibliografiske detaljer
Udgivet i:Angew Chem Int Ed Engl
Main Authors: Partridge, Benjamin M., Callingham, Michael, Lewis, William, Lam, Hon Wai
Format: Artigo
Sprog:Inglês
Udgivet: John Wiley and Sons Inc. 2017
Fag:
Online adgang:https://ncbi.nlm.nih.gov/pmc/articles/PMC5488243/
https://ncbi.nlm.nih.gov/pubmed/28523779
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201703155
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