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Control of Olefin Geometry in Macrocyclic Ring-Closing Metathesis Using a Removable Silyl Group
Introduction of a silyl group to one of the internal olefin positions in di-olefinic substrates is able to control effectively the resulting olefin geometry in ring-closing metathesis. The application of this method to a range of macrocyclic E-alkenyl siloxanes is described. Protodesilylation of alk...
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| Publicado en: | J Am Chem Soc |
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| Autores principales: | , , , , , |
| Formato: | Artigo |
| Lenguaje: | Inglês |
| Publicado: |
2011
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| Materias: | |
| Acceso en línea: | https://ncbi.nlm.nih.gov/pmc/articles/PMC5436309/ https://ncbi.nlm.nih.gov/pubmed/21557625 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja202012s |
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