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Control of Olefin Geometry in Macrocyclic Ring-Closing Metathesis Using a Removable Silyl Group

Introduction of a silyl group to one of the internal olefin positions in di-olefinic substrates is able to control effectively the resulting olefin geometry in ring-closing metathesis. The application of this method to a range of macrocyclic E-alkenyl siloxanes is described. Protodesilylation of alk...

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Publicat a:J Am Chem Soc
Autors principals: Wang, Yikai, Jimenez, Miguel, Hansen, Anders S., Raiber, Eun-Ang, Schreiber, Stuart L., Young, Damian W.
Format: Artigo
Idioma:Inglês
Publicat: 2011
Matèries:
Accés en línia:https://ncbi.nlm.nih.gov/pmc/articles/PMC5436309/
https://ncbi.nlm.nih.gov/pubmed/21557625
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja202012s
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