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An efficient method for synthesising unsymmetrical silaketals: substrates for ring-closing, including macrocycle-closing, metathesis

Diisopropylsilyl ethers were activated with N-bromosuccinimide, and reacted with a fluorous-tagged alcohol, to yield tethered substrates for ring-closing metathesis reactions.

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Detalhes bibliográficos
Main Authors: Cordier, Christopher, Morton, Daniel, Leach, Stuart, Woodhall, Thomas, O'Leary-Steele, Catherine, Warriner, Stuart, Nelson, Adam
Formato: Artigo
Idioma:Inglês
Publicado em: Royal Society of Chemistry 2008
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC2442217/
https://ncbi.nlm.nih.gov/pubmed/18452006
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/b804769n
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