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Highly selective one-step dehydration, decarboxylation and hydrogenation of citric acid to methylsuccinic acid

The one-step dehydration, decarboxylation and hydrogenation of the bio-based and widely available citric acid is presented. This reaction sequence yields methylsuccinic acid with yields of up to 89%. Optimal balances between the reaction rates of the different steps were found by varying the hydroge...

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Detalhes bibliográficos
Publicado no:Chem Sci
Main Authors: Verduyckt, Jasper, De Vos, Dirk E.
Formato: Artigo
Idioma:Inglês
Publicado em: Royal Society of Chemistry 2017
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC5431699/
https://ncbi.nlm.nih.gov/pubmed/28553496
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c6sc04541c
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