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One-step selective hydroxylation of benzene to phenol with hydrogen peroxide catalysed by copper complexes incorporated into mesoporous silica–alumina

Benzene was hydroxylated with hydrogen peroxide (H(2)O(2)) in the presence of catalytic amounts of copper complexes in acetone to yield phenol at 298 K. At higher temperatures, phenol was further hydroxylated with H(2)O(2) by catalysis of copper complexes to yield p-benzoquinone. The kinetic study r...

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Wedi'i Gadw mewn:
Manylion Llyfryddiaeth
Cyhoeddwyd yn:Chem Sci
Prif Awduron: Yamada, Mihoko, Karlin, Kenneth D., Fukuzumi, Shunichi
Fformat: Artigo
Iaith:Inglês
Cyhoeddwyd: Royal Society of Chemistry 2016
Pynciau:
Mynediad Ar-lein:https://ncbi.nlm.nih.gov/pmc/articles/PMC4951108/
https://ncbi.nlm.nih.gov/pubmed/27453774
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c5sc04312c
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