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One-step selective hydroxylation of benzene to phenol with hydrogen peroxide catalysed by copper complexes incorporated into mesoporous silica–alumina

Benzene was hydroxylated with hydrogen peroxide (H(2)O(2)) in the presence of catalytic amounts of copper complexes in acetone to yield phenol at 298 K. At higher temperatures, phenol was further hydroxylated with H(2)O(2) by catalysis of copper complexes to yield p-benzoquinone. The kinetic study r...

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Gorde:
Xehetasun bibliografikoak
Argitaratua izan da:Chem Sci
Egile Nagusiak: Yamada, Mihoko, Karlin, Kenneth D., Fukuzumi, Shunichi
Formatua: Artigo
Hizkuntza:Inglês
Argitaratua: Royal Society of Chemistry 2016
Gaiak:
Sarrera elektronikoa:https://ncbi.nlm.nih.gov/pmc/articles/PMC4951108/
https://ncbi.nlm.nih.gov/pubmed/27453774
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c5sc04312c
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