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One-step selective hydroxylation of benzene to phenol with hydrogen peroxide catalysed by copper complexes incorporated into mesoporous silica–alumina

Benzene was hydroxylated with hydrogen peroxide (H(2)O(2)) in the presence of catalytic amounts of copper complexes in acetone to yield phenol at 298 K. At higher temperatures, phenol was further hydroxylated with H(2)O(2) by catalysis of copper complexes to yield p-benzoquinone. The kinetic study r...

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Detalhes bibliográficos
Publicado no:Chem Sci
Main Authors: Yamada, Mihoko, Karlin, Kenneth D., Fukuzumi, Shunichi
Formato: Artigo
Idioma:Inglês
Publicado em: Royal Society of Chemistry 2016
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC4951108/
https://ncbi.nlm.nih.gov/pubmed/27453774
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c5sc04312c
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