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A highly selective decarboxylative deuteration of carboxylic acids
In this paper, we report a mild and practical method for precise deuteration of aliphatic carboxylic acids by synergistic photoredox and HAT catalysis. The reaction delivers excellent D-incorporation (up to 99%) at predicted sites even in substrates bearing reactive C–H bonds or versatile functional...
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| Pubblicato in: | Chem Sci |
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| Autori principali: | , , , , , |
| Natura: | Artigo |
| Lingua: | Inglês |
| Pubblicazione: |
The Royal Society of Chemistry
2021
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| Soggetti: | |
| Accesso online: | https://ncbi.nlm.nih.gov/pmc/articles/PMC8179560/ https://ncbi.nlm.nih.gov/pubmed/34163771 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/d1sc00528f |
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