Llwytho...

A highly selective decarboxylative deuteration of carboxylic acids

In this paper, we report a mild and practical method for precise deuteration of aliphatic carboxylic acids by synergistic photoredox and HAT catalysis. The reaction delivers excellent D-incorporation (up to 99%) at predicted sites even in substrates bearing reactive C–H bonds or versatile functional...

Disgrifiad llawn

Wedi'i Gadw mewn:
Manylion Llyfryddiaeth
Cyhoeddwyd yn:Chem Sci
Prif Awduron: Li, Nian, Ning, Yunyun, Wu, Xiaopeng, Xie, Jin, Li, Weipeng, Zhu, Chengjian
Fformat: Artigo
Iaith:Inglês
Cyhoeddwyd: The Royal Society of Chemistry 2021
Pynciau:
Mynediad Ar-lein:https://ncbi.nlm.nih.gov/pmc/articles/PMC8179560/
https://ncbi.nlm.nih.gov/pubmed/34163771
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/d1sc00528f
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