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Selective anomeric acetylation of unprotected sugars in water
High yielding selective acetylation of only the anomeric hydroxyl of unprotected sugars is possible in aqueous solution using 2-chloro-1,3-dimethylimidazolinium chloride (DMC), thioacetic acid, and a suitable base. The reaction, which may be performed on a multi-gram scale, is stereoselective for su...
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| Pubblicato in: | Chem Sci |
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| Autori principali: | , |
| Natura: | Artigo |
| Lingua: | Inglês |
| Pubblicazione: |
Royal Society of Chemistry
2017
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| Soggetti: | |
| Accesso online: | https://ncbi.nlm.nih.gov/pmc/articles/PMC5424810/ https://ncbi.nlm.nih.gov/pubmed/28553480 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c6sc04667c |
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