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Iridium-catalyzed asymmetric hydrogenation of racemic α-substituted lactones to chiral diols
We report a protocol for the highly efficient iridium-catalyzed asymmetric hydrogenation of racemic α-substituted lactones via dynamic kinetic resolution. Using Ir-SpiroPAP (R)-1d as a catalyst, a wide range of chiral diols were prepared in a high yield (80–95%) with a high enantioselectivity (up to...
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| Gepubliceerd in: | Chem Sci |
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| Hoofdauteurs: | , , , , , |
| Formaat: | Artigo |
| Taal: | Inglês |
| Gepubliceerd in: |
Royal Society of Chemistry
2017
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| Onderwerpen: | |
| Online toegang: | https://ncbi.nlm.nih.gov/pmc/articles/PMC5396509/ https://ncbi.nlm.nih.gov/pubmed/28451302 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c6sc04609f |
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