טוען...
Catalytic Synthesis of N-Heterocycles via Direct C(sp(3))–H Amination Using an Air-Stable Iron(III) Species with a Redox-Active Ligand
[Image: see text] Coordination of FeCl(3) to the redox-active pyridine–aminophenol ligand NNO(H2) in the presence of base and under aerobic conditions generates FeCl(2)(NNO(ISQ)) (1), featuring high-spin Fe(III) and an NNO(ISQ) radical ligand. The complex has an overall S = 2 spin state, as deduced...
שמור ב:
| הוצא לאור ב: | J Am Chem Soc |
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| Main Authors: | , , , , , , , , |
| פורמט: | Artigo |
| שפה: | Inglês |
| יצא לאור: |
American Chemical
Society
2017
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| גישה מקוונת: | https://ncbi.nlm.nih.gov/pmc/articles/PMC5391503/ https://ncbi.nlm.nih.gov/pubmed/28298089 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.7b00270 |
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