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Uncatalyzed Oxidative C−H Amination of 9,10‐Dihydro‐9‐Heteroanthracenes: A Mechanistic Study

A new method for the one‐step C−H amination of xanthene and thioxanthene with sulfonamides is reported, without the need for any metal catalyst. A benzoquinone was employed as a hydride (or two‐electron and one‐proton) acceptor. Moreover, a previously unknown and uncatalyzed reaction between iminoio...

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Vydáno v:Chemistry
Hlavní autoři: van Leest, Nicolaas P., Grooten, Lars, van der Vlugt, Jarl Ivar, de Bruin, Bas
Médium: Artigo
Jazyk:Inglês
Vydáno: John Wiley and Sons Inc. 2019
Témata:
On-line přístup:https://ncbi.nlm.nih.gov/pmc/articles/PMC6563809/
https://ncbi.nlm.nih.gov/pubmed/30793814
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/chem.201900377
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