Cobalt‐Porphyrin‐Catalysed Intramolecular Ring‐Closing C−H Amination of Aliphatic Azides: A Nitrene‐Radical Approach to Saturated Heterocycles

Cobalt‐porphyrin‐catalysed intramolecular ring‐closing C−H bond amination enables direct synthesis of various N‐heterocycles from aliphatic azides. Pyrrolidines, oxazolidines, imidazolidines, isoindolines and tetrahydroisoquinoline can be obtained in good to excellent yields in a single reaction ste...

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Detalhes bibliográficos
Publicado no:Chemistry
Main Authors: Kuijpers, Petrus F., Tiekink, Martijn J., Breukelaar, Willem B., Broere, Daniël L. J., van Leest, Nicolaas P., van der Vlugt, Jarl Ivar, Reek, Joost N. H., de Bruin, Bas
Formato: Artigo
Idioma:Inglês
Publicado em: John Wiley and Sons Inc. 2017
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Full Papers
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC5488222/
https://ncbi.nlm.nih.gov/pubmed/28332743
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/chem.201700358
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