Catalytic Synthesis of N-Heterocycles via Direct C(sp(3))–H Amination Using an Air-Stable Iron(III) Species with a Redox-Active Ligand

[Image: see text] Coordination of FeCl(3) to the redox-active pyridine–aminophenol ligand NNO(H2) in the presence of base and under aerobic conditions generates FeCl(2)(NNO(ISQ)) (1), featuring high-spin Fe(III) and an NNO(ISQ) radical ligand. The complex has an overall S = 2 spin state, as deduced...

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Bibliographic Details
Published in:J Am Chem Soc
Main Authors: Bagh, Bidraha, Broere, Daniël L. J., Sinha, Vivek, Kuijpers, Petrus F., van Leest, Nicolaas P., de Bruin, Bas, Demeshko, Serhiy, Siegler, Maxime A., van der Vlugt, Jarl Ivar
Format: Artigo
Language:Inglês
Published: American Chemical Society 2017
Online Access:https://ncbi.nlm.nih.gov/pmc/articles/PMC5391503/
https://ncbi.nlm.nih.gov/pubmed/28298089
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.7b00270
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