Unpredictable cycloisomerization of 1,11-dien-6-ynes by a common cobalt catalyst

1,11-Dien-6-ynes undergo cycloisomerization in the presence of the cobalt catalytic system CoBr(2)/phosphine ligand/Zn/ZnI(2) giving cyclohexene, diene or cyclopropane structures depending on the type of the phosphine ligand. This unpredictable behaviour suggests that, although the availability of t...

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Publicado en:Beilstein J Org Chem
Autores principales: Suleymanov, Abdusalom A, Vasilyev, Dmitry V, Novikov, Valentin V, Nelyubina, Yulia V, Perekalin, Dmitry S
Formato: Artigo
Lenguaje:Inglês
Publicado: Beilstein-Institut 2017
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Full Research Paper
Acceso en línea:https://ncbi.nlm.nih.gov/pmc/articles/PMC5389203/
https://ncbi.nlm.nih.gov/pubmed/28487757
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.3762/bjoc.13.62
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