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Cycloisomerization of Dienes with Carbophilic Lewis Acids: Mimicking Terpene Biosynthesis with Pt(II) Catalysts
Dicationic Pt(II) complexes containing triphosphine pincer ligands are excellent catalysts for the cycloisomerization of 1,6- and 1,7-dienes into bicyclopropane carbocycles. In analogy to the biosynthetic route to these monoterpene-like compounds, carbocation intermediates are proposed and supported...
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| Hauptverfasser: | , |
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| Format: | Artigo |
| Sprache: | Inglês |
| Veröffentlicht: |
2005
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| Schlagworte: | |
| Online Zugang: | https://ncbi.nlm.nih.gov/pmc/articles/PMC2515936/ https://ncbi.nlm.nih.gov/pubmed/16018665 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ol051277c |
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