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Unpredictable cycloisomerization of 1,11-dien-6-ynes by a common cobalt catalyst
1,11-Dien-6-ynes undergo cycloisomerization in the presence of the cobalt catalytic system CoBr(2)/phosphine ligand/Zn/ZnI(2) giving cyclohexene, diene or cyclopropane structures depending on the type of the phosphine ligand. This unpredictable behaviour suggests that, although the availability of t...
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| Publicado no: | Beilstein J Org Chem |
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| Main Authors: | , , , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
Beilstein-Institut
2017
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC5389203/ https://ncbi.nlm.nih.gov/pubmed/28487757 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.3762/bjoc.13.62 |
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