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Platinum-Catalyzed α,β-Unsaturated Carbene Formation in the Formal Syntheses of Frondosin B and Liphagal
Formal syntheses of tetracyclic terpenoids frondosin B and liphagal are described. Both synthetic routes rely on the use of platinum-catalyzed α,β-unsaturated carbene formation for the key C–C bond forming transformations. The successful route toward frondosin B utilizes a formal (4 + 3) cycloadditi...
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| Publicado no: | Org Lett |
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| Main Authors: | , , , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2016
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC5369019/ https://ncbi.nlm.nih.gov/pubmed/27997203 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acs.orglett.6b03682 |
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