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α,β-Unsaturated Acyl Azoliums from N-Heterocyclic Carbene Catalyzed Reactions: Observation and Mechanistic Investigation()

Catalytically generated acyl azoliums I and their α,β-unsaturated counterparts II are thought to be key reactive intermediates in a rapidly growing number of transformations promoted by N-heterocyclic carbene (NHC) catalysts.([1]) Acyl azoliums are invoked in the postulated catalytic cycles of nearl...

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Main Authors: Mahatthananchai, Jessada, Zheng, Pinguan, Bode, Jeffrey W.
Formato: Artigo
Idioma:Inglês
Publicado: 2011
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Acceso en liña:https://ncbi.nlm.nih.gov/pmc/articles/PMC3189509/
https://ncbi.nlm.nih.gov/pubmed/21308930
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201005352
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