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α,β-Unsaturated Acyl Azoliums from N-Heterocyclic Carbene Catalyzed Reactions: Observation and Mechanistic Investigation()
Catalytically generated acyl azoliums I and their α,β-unsaturated counterparts II are thought to be key reactive intermediates in a rapidly growing number of transformations promoted by N-heterocyclic carbene (NHC) catalysts.([1]) Acyl azoliums are invoked in the postulated catalytic cycles of nearl...
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| Principais autores: | , , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2011
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3189509/ https://ncbi.nlm.nih.gov/pubmed/21308930 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201005352 |
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