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Acyl Donor Intermediates in N‐Heterocyclic Carbene Catalysis: Acyl Azolium or Azolium Enolate?

Azolium enolates and acyl azolium cations have been proposed as intermediates in numerous N‐heterocyclic carbene (NHC) catalyzed transformations. Acetyl azolium enolates were generated from the reaction of 2‐propenyl acetate with both saturated (SIPr) and aromatic (IPr) NHCs, isolated, and character...

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Detalhes bibliográficos
Publicado no:Angew Chem Int Ed Engl
Main Authors: Biswas, Animesh, Neudörfl, Jörg‐M., Schlörer, Nils E., Berkessel, Albrecht
Formato: Artigo
Idioma:Inglês
Publicado em: John Wiley and Sons Inc. 2021
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC7986403/
https://ncbi.nlm.nih.gov/pubmed/33140529
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.202010348
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