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Iridium-Catalyzed Enantioselective Allylic Substitution of Enol Silanes from Vinylogous Esters and Amides

The enol silanes of vinylogous esters and amides are classic dienes for Diels–Alder reactions. Here, we report their reactivity as nucleophiles in Ir-catalyzed, enantioselective allylic substitution reactions. A variety of allylic carbonates react with these nucleophiles to give allylated products i...

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Bibliografske podrobnosti
izdano v:J Am Chem Soc
Main Authors: Chen, Ming, Hartwig, John F.
Format: Artigo
Jezik:Inglês
Izdano: 2015
Teme:
Online dostop:https://ncbi.nlm.nih.gov/pmc/articles/PMC5342901/
https://ncbi.nlm.nih.gov/pubmed/26441002
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.5b09980
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