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Tritium-Labeled Compounds. XI. Mechanism for the Oxidation of Aldehydes and Aldoses-1-t With Sodium Chlorite

Measurements of kinetic isotope-effects (k*/k) for the oxidation of ten aldoses-1-t with sodium chlorite in acid solution gave values ranging from 0.56 to 0.75, with an average of 0.66. The values show that the C1—H* bond is not ruptured in the rate-determining step. For the reaction, a mechanism is...

पूर्ण विवरण

में बचाया:
ग्रंथसूची विवरण
में प्रकाशित:J Res Natl Bur Stand A Phys Chem
मुख्य लेखकों: Isbell, Horace S., Sniegoski, Lorna T.
स्वरूप: Artigo
भाषा:Inglês
प्रकाशित: [Gaithersburg, MD] : U.S. Dept. of Commerce, National Institute of Standards and Technology 1964
विषय:
ऑनलाइन पहुंच:https://ncbi.nlm.nih.gov/pmc/articles/PMC5327691/
https://ncbi.nlm.nih.gov/pubmed/31834724
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.6028/jres.068A.027
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