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Tritium-Labeled Compounds. XI. Mechanism for the Oxidation of Aldehydes and Aldoses-1-t With Sodium Chlorite
Measurements of kinetic isotope-effects (k*/k) for the oxidation of ten aldoses-1-t with sodium chlorite in acid solution gave values ranging from 0.56 to 0.75, with an average of 0.66. The values show that the C1—H* bond is not ruptured in the rate-determining step. For the reaction, a mechanism is...
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| Publicado no: | J Res Natl Bur Stand A Phys Chem |
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| Main Authors: | , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
[Gaithersburg, MD] : U.S. Dept. of Commerce, National Institute of Standards and Technology
1964
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC5327691/ https://ncbi.nlm.nih.gov/pubmed/31834724 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.6028/jres.068A.027 |
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