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Tritium-Labeled Compounds IX. Determination of Isotope Effects in Reactions Yielding Water-t from Nonvolatile Reactants. Oxidation of Aldoses-1-t With Iodine

A convenient method is presented for estimating isotope effects in reactions which yield water-t. The water-t is separated by freeze-drying, and k*/k is calculated from the extent of the reaction and the ratio of the radioactivity of the water-t to that of the initial reactant. Application of the me...

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Detalhes bibliográficos
Publicado no:J Res Natl Bur Stand A Phys Chem
Main Authors: Isbell, Horace S., Sniegoski, Lorna T.
Formato: Artigo
Idioma:Inglês
Publicado em: [Gaithersburg, MD] : U.S. Dept. of Commerce, National Institute of Standards and Technology 1963
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC5322772/
https://ncbi.nlm.nih.gov/pubmed/31580600
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.6028/jres.067A.054
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