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Tritium-Labeled Compounds IX. Determination of Isotope Effects in Reactions Yielding Water-t from Nonvolatile Reactants. Oxidation of Aldoses-1-t With Iodine
A convenient method is presented for estimating isotope effects in reactions which yield water-t. The water-t is separated by freeze-drying, and k*/k is calculated from the extent of the reaction and the ratio of the radioactivity of the water-t to that of the initial reactant. Application of the me...
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| Publicat a: | J Res Natl Bur Stand A Phys Chem |
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| Autors principals: | , |
| Format: | Artigo |
| Idioma: | Inglês |
| Publicat: |
[Gaithersburg, MD] : U.S. Dept. of Commerce, National Institute of Standards and Technology
1963
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| Matèries: | |
| Accés en línia: | https://ncbi.nlm.nih.gov/pmc/articles/PMC5322772/ https://ncbi.nlm.nih.gov/pubmed/31580600 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.6028/jres.067A.054 |
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