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Tritium-Labeled Compounds X. Isotope Effects in the Oxidation of Aldoses-1-t With Bromine

Tritium isotope effects have been used in bromine oxidation studies of aldoses to evaluate two reaction paths previously postulated by Isbell and Pigman, namely, direct oxidation and oxidation after anomerization. Because the former path involves a primary isotope effect (k*/k = 0.14, approximately)...

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Wedi'i Gadw mewn:
Manylion Llyfryddiaeth
Cyhoeddwyd yn:J Res Natl Bur Stand A Phys Chem
Prif Awduron: Isbell, Horace S., Sniegoski, Lorna T.
Fformat: Artigo
Iaith:Inglês
Cyhoeddwyd: [Gaithersburg, MD] : U.S. Dept. of Commerce, National Institute of Standards and Technology 1964
Pynciau:
Mynediad Ar-lein:https://ncbi.nlm.nih.gov/pmc/articles/PMC5323084/
https://ncbi.nlm.nih.gov/pubmed/31834698
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.6028/jres.068A.013
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