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Tritium-Labeled Compounds X. Isotope Effects in the Oxidation of Aldoses-1-t With Bromine

Tritium isotope effects have been used in bromine oxidation studies of aldoses to evaluate two reaction paths previously postulated by Isbell and Pigman, namely, direct oxidation and oxidation after anomerization. Because the former path involves a primary isotope effect (k*/k = 0.14, approximately)...

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Detalhes bibliográficos
Publicado no:J Res Natl Bur Stand A Phys Chem
Main Authors: Isbell, Horace S., Sniegoski, Lorna T.
Formato: Artigo
Idioma:Inglês
Publicado em: [Gaithersburg, MD] : U.S. Dept. of Commerce, National Institute of Standards and Technology 1964
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC5323084/
https://ncbi.nlm.nih.gov/pubmed/31834698
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.6028/jres.068A.013
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