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Tritium-Labeled Compounds X. Isotope Effects in the Oxidation of Aldoses-1-t With Bromine

Tritium isotope effects have been used in bromine oxidation studies of aldoses to evaluate two reaction paths previously postulated by Isbell and Pigman, namely, direct oxidation and oxidation after anomerization. Because the former path involves a primary isotope effect (k*/k = 0.14, approximately)...

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Pubblicato in:J Res Natl Bur Stand A Phys Chem
Autori principali: Isbell, Horace S., Sniegoski, Lorna T.
Natura: Artigo
Lingua:Inglês
Pubblicazione: [Gaithersburg, MD] : U.S. Dept. of Commerce, National Institute of Standards and Technology 1964
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Accesso online:https://ncbi.nlm.nih.gov/pmc/articles/PMC5323084/
https://ncbi.nlm.nih.gov/pubmed/31834698
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.6028/jres.068A.013
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