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Diastereoselective Organocatalytic Addition of α-Angelica Lactone to β-Halo-α-Ketoesters
A quinidine-catalyzed diastereoselective addition of α-angelica lactone to β-halo-α-ketoesters is reported. The α-angelica lactone displays unusual regioselectivity in this reaction, acting as a nucleophile at the α-position to provide fully substituted glycolic esters with three contiguous stereoce...
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| Veröffentlicht in: | J Org Chem |
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| Hauptverfasser: | , , , |
| Format: | Artigo |
| Sprache: | Inglês |
| Veröffentlicht: |
2017
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| Schlagworte: | |
| Online Zugang: | https://ncbi.nlm.nih.gov/pmc/articles/PMC5324730/ https://ncbi.nlm.nih.gov/pubmed/28164699 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acs.joc.6b03059 |
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