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Stereoconvergent Conjugate Addition of Arylboronic Acids to α-Angelica Lactone Derivatives: Synthesis of Stereochemically Complex γ-Butyrolactones

Catalyzed stereoconvergent 1,4-additions to unsaturated carbonyls are rare but of high potential value. This letter details the development of enantioselective arylation reactions of boronic acids and β,γ-butenolides. These reactions are catalyzed by commercially available hydroxy[(S)-BINAP]-rhodium...

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Vydáno v:ACS Catal
Hlavní autoři: Griswold, Jessica A., Johnson, Jeffrey S.
Médium: Artigo
Jazyk:Inglês
Vydáno: 2019
Témata:
On-line přístup:https://ncbi.nlm.nih.gov/pmc/articles/PMC8018650/
https://ncbi.nlm.nih.gov/pubmed/33815896
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acscatal.9b04405
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