تحميل...
O–H Activation by an Unexpected Ferryl Intermediate during Catalysis by 2-Hydroxyethylphosphonate Dioxygenase
[Image: see text] Activation of O–H bonds by inorganic metal-oxo complexes has been documented, but no cognate enzymatic process is known. Our mechanistic analysis of 2-hydroxyethylphosphonate dioxygenase (HEPD), which cleaves the C1–C2 bond of its substrate to afford hydroxymethylphosphonate on the...
محفوظ في:
| الحاوية / القاعدة: | J Am Chem Soc |
|---|---|
| المؤلفون الرئيسيون: | , , , , , , , , |
| التنسيق: | Artigo |
| اللغة: | Inglês |
| منشور في: |
American Chemical
Society
2017
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| الوصول للمادة أونلاين: | https://ncbi.nlm.nih.gov/pmc/articles/PMC5302023/ https://ncbi.nlm.nih.gov/pubmed/28092705 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.6b12147 |
| الوسوم: |
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