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A Chiral Nitrogen Ligand for Enantioselective, Iridium-Catalyzed Silylation of Aromatic C-H Bonds

Iridium catalysts containing dative nitrogen ligands are highly active for the borylation and silylation of C-H bonds, but chiral analogs of these catalysts for enantioselective silylation reactions have not been developed. We report a new chiral pyridinyloxazoline ligand for enantioselective, intra...

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Detalles Bibliográficos
Publicado en:Angew Chem Int Ed Engl
Main Authors: Su, Bo, Zhou, Tai-Gang, Li, Xian-Wei, Shao, Xiao-Ru, Xu, Pei-Lin, Wu, Wen-Lian, Hartwig, John F., Shi, Zhang-Jie
Formato: Artigo
Idioma:Inglês
Publicado: 2016
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Acceso en liña:https://ncbi.nlm.nih.gov/pmc/articles/PMC5293510/
https://ncbi.nlm.nih.gov/pubmed/27976482
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201609939
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