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C-H and C-N Activation at Redox-Active Pyridine Complexes of Iron
Pyridine activation by inexpensive iron catalysts has great utility, but the steps through which iron species can break the strong (105–111 kcal/mol) C-H bonds of pyridine substrates are unknown. In this work, we report the rapid room-temperature cleavage of C-H bonds in pyridine, 4-tert-butylpyridi...
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| Publicado no: | Angew Chem Int Ed Engl |
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| Main Authors: | , , , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2016
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC5266524/ https://ncbi.nlm.nih.gov/pubmed/28000416 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201610679 |
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