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A Multi-iron System Capable of Rapid N(2) Formation and N(2) Cleavage

[Image: see text] The six-electron oxidation of two nitrides to N(2) is a key step of ammonia synthesis and decomposition reactions on surfaces. In molecular complexes, nitride coupling has been observed with terminal nitrides, but not with bridging nitride complexes that more closely resemble catal...

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Pubblicato in:J Am Chem Soc
Autori principali: MacLeod, K. Cory, Vinyard, David J., Holland, Patrick L.
Natura: Artigo
Lingua:Inglês
Pubblicazione: American Chemical Society 2014
Accesso online:https://ncbi.nlm.nih.gov/pmc/articles/PMC4353015/
https://ncbi.nlm.nih.gov/pubmed/25004280
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja505193z
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