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Stepwise N–H bond formation from N(2)-derived iron nitride, imide and amide intermediates to ammonia

Reduction of N(2) to ammonia in nature and in electrocatalysis takes place through 1-proton/1-electron steps, motivating efforts to experimentally study the steps during proton/electron transfer to well-characterized N(2)-derived species with bridging nitrides. We report here the protonation and red...

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Detalhes bibliográficos
Publicado no:Chem Sci
Main Authors: MacLeod, K. Cory, McWilliams, Sean F., Mercado, Brandon Q., Holland, Patrick L.
Formato: Artigo
Idioma:Inglês
Publicado em: Royal Society of Chemistry 2016
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC5207225/
https://ncbi.nlm.nih.gov/pubmed/28066537
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c6sc00423g
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