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Acidity and basicity interplay in amide and imide self-association
Amides dimerise more strongly than imides despite their lower acidity. Such an unexpected result has been rationalised in terms of the Jorgensen Secondary Interactions Hypothesis (JSIH) that involves the spectator (C[double bond, length as m-dash]O(S)) and H-bonded (C[double bond, length as m-dash]O...
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| Publicado no: | Chem Sci |
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| Main Authors: | , , , , , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
Royal Society of Chemistry
2018
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC5956980/ https://ncbi.nlm.nih.gov/pubmed/29896381 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c8sc01020j |
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