Acidity and basicity interplay in amide and imide self-association

Amides dimerise more strongly than imides despite their lower acidity. Such an unexpected result has been rationalised in terms of the Jorgensen Secondary Interactions Hypothesis (JSIH) that involves the spectator (C[double bond, length as m-dash]O(S)) and H-bonded (C[double bond, length as m-dash]O...

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Publicat a:Chem Sci
Autors principals: Vallejo Narváez, Wilmer E., Jiménez, Eddy I., Romero-Montalvo, Eduardo, Sauza-de la Vega, Arturo, Quiroz-García, Beatriz, Hernández-Rodríguez, Marcos, Rocha-Rinza, Tomás
Format: Artigo
Idioma:Inglês
Publicat: Royal Society of Chemistry 2018
Matèries:
Chemistry
Accés en línia:https://ncbi.nlm.nih.gov/pmc/articles/PMC5956980/
https://ncbi.nlm.nih.gov/pubmed/29896381
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c8sc01020j
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