Acidity and basicity interplay in amide and imide self-association

Amides dimerise more strongly than imides despite their lower acidity. Such an unexpected result has been rationalised in terms of the Jorgensen Secondary Interactions Hypothesis (JSIH) that involves the spectator (C[double bond, length as m-dash]O(S)) and H-bonded (C[double bond, length as m-dash]O...

Ausführliche Beschreibung

Gespeichert in:
Bibliographische Detailangaben
Veröffentlicht in:Chem Sci
Hauptverfasser: Vallejo Narváez, Wilmer E., Jiménez, Eddy I., Romero-Montalvo, Eduardo, Sauza-de la Vega, Arturo, Quiroz-García, Beatriz, Hernández-Rodríguez, Marcos, Rocha-Rinza, Tomás
Format: Artigo
Sprache:Inglês
Veröffentlicht: Royal Society of Chemistry 2018
Schlagworte:
Chemistry
Online Zugang:https://ncbi.nlm.nih.gov/pmc/articles/PMC5956980/
https://ncbi.nlm.nih.gov/pubmed/29896381
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c8sc01020j
Tags: Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!

Ähnliche Einträge