Homolytic N–H Activation of Ammonia: Hydrogen Transfer of Parent Iridium Ammine, Amide, Imide, and Nitride Species

[Image: see text] The redox series [Ir(n)(NH(x))(PNP)] (n = II–IV, x = 3–0; PNP = N(CHCHPtBu(2))(2)) was examined with respect to electron, proton, and hydrogen atom transfer steps. The experimental and computational results suggest that the Ir(III) imido species [Ir(NH)(PNP)] is not stable but unde...

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Publicado en:Inorg Chem
Main Authors: Scheibel, Markus G., Abbenseth, Josh, Kinauer, Markus, Heinemann, Frank W., Würtele, Christian, de Bruin, Bas, Schneider, Sven
Formato: Artigo
Idioma:Inglês
Publicado: American Chemical Society 2015
Acceso en liña:https://ncbi.nlm.nih.gov/pmc/articles/PMC4597254/
https://ncbi.nlm.nih.gov/pubmed/26192601
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acs.inorgchem.5b00829
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