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An iridium(iii/iv/v) redox series featuring a terminal imido complex with triplet ground state
The iridium(iii/iv/v) imido redox series [Ir(NtBu){N(CHCHPtBu(2))(2)}](0/+/2+) was synthesized and examined spectroscopically, magnetically, crystallographically and computationally. The monocationic iridium(iv) imide exhibits an electronic doublet ground state with considerable ‘imidyl’ character a...
Shranjeno v:
| izdano v: | Chem Sci |
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| Main Authors: | , , , , , , , , , , |
| Format: | Artigo |
| Jezik: | Inglês |
| Izdano: |
Royal Society of Chemistry
2018
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| Teme: | |
| Online dostop: | https://ncbi.nlm.nih.gov/pmc/articles/PMC5944377/ https://ncbi.nlm.nih.gov/pubmed/29780564 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c8sc01113c |
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