An iridium(iii/iv/v) redox series featuring a terminal imido complex with triplet ground state

The iridium(iii/iv/v) imido redox series [Ir(NtBu){N(CHCHPtBu(2))(2)}](0/+/2+) was synthesized and examined spectroscopically, magnetically, crystallographically and computationally. The monocationic iridium(iv) imide exhibits an electronic doublet ground state with considerable ‘imidyl’ character a...

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Vydáno v:Chem Sci
Hlavní autoři: Kinauer, Markus, Diefenbach, Martin, Bamberger, Heiko, Demeshko, Serhiy, Reijerse, Edward J., Volkmann, Christian, Würtele, Christian, van Slageren, Joris, de Bruin, Bas, Holthausen, Max C., Schneider, Sven
Médium: Artigo
Jazyk:Inglês
Vydáno: Royal Society of Chemistry 2018
Témata:
Chemistry
On-line přístup:https://ncbi.nlm.nih.gov/pmc/articles/PMC5944377/
https://ncbi.nlm.nih.gov/pubmed/29780564
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c8sc01113c
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