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Geometric and redox flexibility of pyridine as a redox-active ligand that can reversibly accept one or two electrons
A low-coordinate iron(I) species can reversibly reduce pyridine, either by one electron to give a new C-C bond, or by two electrons to give a pyridine-derived bridge with an unprecedented μ-η(1):η(3) binding mode.
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| Main Authors: | , , , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2014
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC4169077/ https://ncbi.nlm.nih.gov/pubmed/25111358 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c4cc05495d |
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