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Geometric and redox flexibility of pyridine as a redox-active ligand that can reversibly accept one or two electrons

A low-coordinate iron(I) species can reversibly reduce pyridine, either by one electron to give a new C-C bond, or by two electrons to give a pyridine-derived bridge with an unprecedented μ-η(1):η(3) binding mode.

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Bibliografische gegevens
Hoofdauteurs: Lewis, Richard A., MacLeod, K. Cory, Mercado, Brandon Q., Holland, Patrick L.
Formaat: Artigo
Taal:Inglês
Gepubliceerd in: 2014
Onderwerpen:
Online toegang:https://ncbi.nlm.nih.gov/pmc/articles/PMC4169077/
https://ncbi.nlm.nih.gov/pubmed/25111358
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c4cc05495d
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