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Mechanism, reactivity, and regioselectivity in rhodium-catalyzed asymmetric ring-opening reactions of oxabicyclic alkenes: a DFT Investigation

The origin of the enantio- and regioselectivity of ring-opening reaction of oxabicyclic alkenes catalyzed by rhodium/Josiphos has been examined using M06-2X density functional theory(DFT). DFT calculations predict a 98% ee for the enantioselectivity and only the 1,2-trans product as one regio- and d...

詳細記述

保存先:
書誌詳細
出版年:Sci Rep
主要な著者: Qi, Zheng-Hang, Zhang, Yi, Gao, Yun, Zhang, Ye, Wang, Xing-Wang, Wang, Yong
フォーマット: Artigo
言語:Inglês
出版事項: Nature Publishing Group 2017
主題:
オンライン・アクセス:https://ncbi.nlm.nih.gov/pmc/articles/PMC5225450/
https://ncbi.nlm.nih.gov/pubmed/28074930
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1038/srep40491
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