Загрузка...

Rhodium-catalyzed asymmetric ring opening reactions of oxabicyclic alkenes: Catalyst and substrate studies leading to a mechanistic working model

Catalyst and substrate studies have been performed on the rhodium-catalyzed asymmetric ring opening reaction. A working model is advanced that involves oxidative insertion with retention to form an organorhodium intermediate that then undergoes nucleophilic attack with inversion. Kinetic and competi...

Полное описание

Сохранить в:
Библиографические подробности
Главные авторы: Lautens, Mark, Fagnou, Keith
Формат: Artigo
Язык:Inglês
Опубликовано: National Academy of Sciences 2004
Предметы:
Online-ссылка:https://ncbi.nlm.nih.gov/pmc/articles/PMC397404/
https://ncbi.nlm.nih.gov/pubmed/15067134
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1073/pnas.0307271101
Метки: Добавить метку
Нет меток, Требуется 1-ая метка записи!