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Rhodium-catalyzed asymmetric ring opening reactions of oxabicyclic alkenes: Catalyst and substrate studies leading to a mechanistic working model

Catalyst and substrate studies have been performed on the rhodium-catalyzed asymmetric ring opening reaction. A working model is advanced that involves oxidative insertion with retention to form an organorhodium intermediate that then undergoes nucleophilic attack with inversion. Kinetic and competi...

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Hlavní autoři: Lautens, Mark, Fagnou, Keith
Médium: Artigo
Jazyk:Inglês
Vydáno: National Academy of Sciences 2004
Témata:
On-line přístup:https://ncbi.nlm.nih.gov/pmc/articles/PMC397404/
https://ncbi.nlm.nih.gov/pubmed/15067134
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1073/pnas.0307271101
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