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Synthesis of Aza-Rocaglates via ESIPT-Mediated (3+2) Photocycloaddition

Synthesis of aza-rocaglates, nitrogen-containing analogues of the rocaglate natural products, is reported. The route features ESIPT-mediated (3+2) photocycloaddition of 1-alkyl-2-aryl-3-hydroxyquinolinones with the dipolarophile methyl cinnamate. A continuous photoflow reactor was utilized for photo...

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Bibliografski detalji
Izdano u:Chemistry
Glavni autori: Wang, Wenyu, Cencic, Regina, Whitesell, L. Luke, Pelletier, Jerry, Porco, John A.
Format: Artigo
Jezik:Inglês
Izdano: 2016
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Online pristup:https://ncbi.nlm.nih.gov/pmc/articles/PMC5224829/
https://ncbi.nlm.nih.gov/pubmed/27338157
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/chem.201602953
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