Total Syntheses of the Isomeric Aglain Natural Products Foveoglin A and Perviridisin B via Selective ESIPT Photocycloaddition

Selective ESIPT photocycloaddition of 3-hydroxyflavones with trans, trans-1,4-diphenyl-1,3-butadiene is described. Using this methodology, total syntheses of the natural products (±)-foveoglin A and (±)-perviridisin B have been accomplished. Enantioselective ESIPT photocycloaddition using TADDOLs as...

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Gepubliceerd in:Angew Chem Int Ed Engl
Hoofdauteurs: Wang, Wenyu, Clay, Anthony, Krishnan, Retheesh, Lajkiewicz, Neil J., Brown, Lauren E., Sivaguru, Jayaraman, Porco, John A.
Formaat: Artigo
Taal:Inglês
Gepubliceerd in: 2017
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Article
Online toegang:https://ncbi.nlm.nih.gov/pmc/articles/PMC5876029/
https://ncbi.nlm.nih.gov/pubmed/28950418
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201707539
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